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Chemistry, physics and science would never be the same again. New concepts like hybridization were also discovered. This replaced well-defined orbits in the atom with the concept of orbitals. Max Born would later discover that in an atom, the square of the wave function gives the probability of finding the electron in that region. Schrödinger’s equation has been universally recognized as one of the greatest achievements of twentieth century science, containing much of physics and in principle, all of chemistry. The replacement waves describe the individual states of the quantum system, and their amplitudes give the relative importance of that particular state to the whole system.
#Schrodinger chemistry series
The solution of Schrödinger’s equation – the wave function for the system can, using Fourier analysis, be replaced by an infinite series of the wave functions of the individual states, which are natural harmonics of each other. The physical interpretation of this wave remains one of the greatest philosophical problems in modern physics. The solution to Schrödinger’s equation is a wave that describes the quantum aspects of a system. Schrödinger was inspired by de Broglie’s idea of wave-particle duality. Schrödinger did not like Heisenberg’s formulation of quantum mechanics – matrix mechanics – since it lacked visualization and was mostly mathematical. The equation was revolutionary as it solved one of the greatest problems in the quantum-mechanical model of the atom. This equation brought him the 1933 Nobel Prize in physics, along with Paul Dirac.
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The time-dependent version of Schrödinger’s equation also relates the Hamiltonian with time. The equation describes the Hamiltonian operator, which when operated on an abstract mathematical function called the wave function, produced energy as a result. He came up with an equation which could be used to find the energy states of an atom. As his background with eigenvalue problems would suggest, he believed that atomic spectra should be determined by some kind of eigenvalue problem. His greatest achievement, however, was yet to come.Įrwin Schrödinger was not happy with Niels Bohr’s old quantum theory. During his time at the University of Zurich, Schrödinger published a lot of papers on thermodynamics. Schrödinger mastered the concept of eigenvalues in continuous media, and did a lot of experimenting. He also had interests in poetry and philosophy.Īt the University of Vienna, Schrödinger met many talented physicists, including Ludwig Boltzmann’s successor Fritz Hasenöhrl, and Franz Exner. On 12th August 1887, a man who would go on to revolutionize not only the field of physics, but also biology, was born.įrom a very young age, Erwin Schrödinger had shown immense talent for mathematics and physics.